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[MoN(NPPh3)3] – ein monomerer Nitrido-Komplex des Molybdäns

✍ Scribed by Armin Dietrich; Bernhard Neumüller; Kurt Dehnicke

Publisher
John Wiley and Sons
Year
1998
Tongue
German
Weight
70 KB
Volume
624
Category
Article
ISSN
0372-7874

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✦ Synopsis

MoN(NPPh 3 ) 3 ] ± a Monomeric Nitrido Complex of Molybdenum Abstract. [MoN(NPPh 3 ) 3 ] (1) has been prepared from [MoCl 3 (N 3 S 2 )] 2 and LiNPPh 3 in toluene suspension in good yields. From n-hexane/dichloromethane solutions 1 ´2 CH 2 Cl 2 crystallizes as colourless single crystals, which were suitable for a crystal structure determination. 1 forms monomeric molecules with a Mo≡N distance of 166.6 pm for the nitrido ligand, which corresponds to a triple bond, and MoN-bonds of 193.6 pm on average of the NPPh 3 ± -ligands, corresponding to shortened single bonds.

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