The influence of various factors on the binding of chloride in cement and the chloride concentration of the pore solution was investigated. It was shown that the pore solutions of samples prepared under addition of chloride taken from the same cement and with identical content of total chloride exhi
Monitoring chloride concentrations in hardened cement pastes using ion selective electrodes
β Scribed by C.P. Atkins; J.D. Scantlebury; P.J. Nedwell; S.P. Blatch
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 344 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0008-8846
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β¦ Synopsis
In a previous paper (1) it has been shown that silver/silver chloride ion selective electrodes are stable in a simulated pore solution and that the potential of these electrodes is a function of chloride ion activity.This has now been compared with chloride concentrations in the pore water, found using a pressure extraction technique, with chlorides added as sodium chloride to the mix water in concentrations ranging from 0.046Mdm" to 0.46Mdm" to ordinary portland cement pastes with a water cement ratio of 0.45. The results show good correlation between concentration added and activity calculated from electromotive force data, with an activity coefficient of 0.46 ;tr 0.07, which agrees with values calculated in the previous paper.
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