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Monitoring chloride concentrations in hardened cement pastes using ion selective electrodes

✍ Scribed by C.P. Atkins; J.D. Scantlebury; P.J. Nedwell; S.P. Blatch


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
344 KB
Volume
26
Category
Article
ISSN
0008-8846

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✦ Synopsis


In a previous paper (1) it has been shown that silver/silver chloride ion selective electrodes are stable in a simulated pore solution and that the potential of these electrodes is a function of chloride ion activity.This has now been compared with chloride concentrations in the pore water, found using a pressure extraction technique, with chlorides added as sodium chloride to the mix water in concentrations ranging from 0.046Mdm" to 0.46Mdm" to ordinary portland cement pastes with a water cement ratio of 0.45. The results show good correlation between concentration added and activity calculated from electromotive force data, with an activity coefficient of 0.46 ;tr 0.07, which agrees with values calculated in the previous paper.


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