A systematic study was performed with mixtures consisting of N2, CH4, C2H6 and C3H8, to investigate experimentally phase equilibria and caloric properties and to test the accuracy of thermodynamic correlations. The first part of this Paper reports results of T-p-x-y measurements on ternary systems i
Molecular thermodynamics of solutions in the normal and critical regions — II. Activity coefficients for the ArN2, C2H6C2H4 and C3H6CO2 systems
✍ Scribed by Jørgen Mollerup; Aage Fredenslund
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 550 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0009-2509
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✦ Synopsis
Activity coefficients for the Ar-N,, CZH6-C2H4, and CSHB-CO2 systems are calculated from published vapour-liquid equilibrium compositions at various pressures and temperatures. The activity coefficients are correlated using a two parameter model based on the principles of molecular thermodynamics. The method is used both in the normal liquid and critical regions. The parameters of the model are shown to be reasonably independent of the temperature for the three systems.
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