An equilibrium phase diagram has been calculated for the CaO-A1203-CaSO4-K20-H20 system at 25°C for several KOH concentrations. These KOH concentrations were chosen to relate to cement pore fluid compositions and published experimental data. In addition to the hydrates found in the CaO-A1203-CaSO4-H
Thermodynamic investigation of the CaOAl2O3CaSO4H2O system at 25°C and the influence of Na2O
✍ Scribed by D. Damidot; F.P. Glasser
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 1023 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0008-8846
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✦ Synopsis
The CaO-AI203-CaSO4-H20 system at 25°C has been investigatedby calcula~ons on the equilibrium solubility surfaces of AH 3, C3AH6, CH, C6AS3H x, C4ASH x and gypsum. The results are in good agreement with the previous experimental data and make it possible to define the hydrates in equilibrium with aqueous solutions of varying compositions. Solid-aqueous equilibria are very sensitive to the presence in the system of additional ions such as sodium.
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The CaO-A1203-CaSO4-H20 system has been investigated at 50°C and 85°C, by calculations of the equilibrium solubility surfaces of AH3, C3AH6, CH, ettringite, monosulphoaluminate and gypsum. The results indicate that monosulphoaluminate becomes a stable phase at elevated temperature. Since ettringite
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