The molecular geometry and molecular dynamics of cdl2 was studied by joint electron diffraction/vibrational spectroscopic analysis. The thermal average (rs) bond length is 2.582 f 0.005 A. The equilibrium configuration of tbe molecule is linear and the equilibrium bond length is estimated to be 2.57
Molecular structure of first-row transition metal dihalides from combined electron diffraction and vibrational spectroscopic analysis
β Scribed by Hargittai, Magdolna; Subbotina, Natalya Yu.; Kolonits, Maria; Gershikov, Alexander G.
- Book ID
- 126688001
- Publisher
- American Institute of Physics
- Year
- 1991
- Tongue
- English
- Weight
- 981 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.460212
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Molecular Structure of SbI3 and BiI3 from Combined Electron Diffraction and Vibrational Spectroscopic Studies. -The experimental results show that molecules of both SbI3 and BiI3 are pyramidal (C3v symmetry; bond lengths and angles are given). The harmonic equilibrium geometries are estimated and t
The equilibrium structures of monomeric gallium and indium trichloride have been determined in harmonic approximation by means of the combined analysis of gas electron diffraction intensities and vibrational frequencies. The molecules are planar and have \(r_{\mathrm{e}}^{h}(\mathrm{M}-\mathrm{Cl})\