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Equilibrium Structure of Monomeric GaCl3 and InCl3 from Combined Analysis of Gas Electron Diffraction and Vibrational Spectroscopic Data

✍ Scribed by N. Vogt; A. Haaland; K.G. Martinsen; J. Vogt

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
271 KB
Volume
163
Category
Article
ISSN
0022-2852

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✦ Synopsis

The equilibrium structures of monomeric gallium and indium trichloride have been determined in harmonic approximation by means of the combined analysis of gas electron diffraction intensities and vibrational frequencies. The molecules are planar and have (r_{\mathrm{e}}^{h}(\mathrm{M}-\mathrm{Cl})) distances of (2.100(3)) and 2.275(3) for (\mathrm{GaCl}{3}) and (\mathrm{InCl}{3}). respectively. Force constants are also obtained for both molecules. a 1994 Academic Press. Inc.

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