The molecular geometry and molecular dynamics of cdl2 was studied by joint electron diffraction/vibrational spectroscopic analysis. The thermal average (rs) bond length is 2.582 f 0.005 A. The equilibrium configuration of tbe molecule is linear and the equilibrium bond length is estimated to be 2.57
Molecular structure of bismuth trichloride from combined electron diffraction and vibrational spectroscopic study
✍ Scribed by Orsolya Töke; Magdolna Hargittai
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 280 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1040-0400
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The equilibrium structures of monomeric gallium and indium trichloride have been determined in harmonic approximation by means of the combined analysis of gas electron diffraction intensities and vibrational frequencies. The molecules are planar and have \(r_{\mathrm{e}}^{h}(\mathrm{M}-\mathrm{Cl})\