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Molecular reorientation of CCl4 and CS2 in alkanes: a 13C and 33S NMR relaxation study

✍ Scribed by Bernard Ancian; Bernard Tiffon; Jacques-Emile Dubois

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
483 KB
Volume
65
Category
Article
ISSN
0009-2614

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✦ Synopsis

Reorientational and angular momentum correlation tmes (\tau_{c}) and (t_{f}) for (\mathrm{CCl}{4}) and (\mathrm{CS}{2}) in alh anes hate been derived from ({ }^{13} \mathrm{C}) spin-spin relasetion times of (\mathrm{CCl}{4}) and ({ }^{33} \mathrm{~S}) linew idths of (\mathrm{CS}{2}). In contrast with neat hquds, molecular reorientution does not obe! (J)-diffusion, but iends towards, 1 -diffusion in larete solents.

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