Molecular Rearrangements. VIII. The Equilibration of 3,3-Dimethyl-2-phenyl- and 2,3-Dimethyl-3-phenyl-3H-indoles 1
✍ Scribed by Evans, Francis J.; Lyle, Gloria G.; Watkins, James; Lyle, Robert E.
- Book ID
- 124071609
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 645 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-3263
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In the title compound, C 24 H 20 N 4 S, the phenyl ring forms a dihedral angle of 49.22 (7) with the indole ring system. The indole and benzothiazole ring systems are both approximately planar, with dihedral angles between the five-and sixmembered rings of 0.98 (7) and 1.28 (5) , respectively. They
In the title compound, C 29 H 25 NO 2 S 2 , the benzene rings of the phenylsulfonyl and the dimethylbenzyl substituents are almost perpendicular to the indole unit, whereas the dihedral angle between the phenyl rings of the phenylsulfanyl and phenylsulfonyl groups is 71.2 (1) . The molecules in the