possibk RSSOIIS for the non-monotonous tempa-aturs dependencf oE the q~~~d-rescmzm~~ emcrgy trmsf'er probability and relative contributions of short-range and long-range forces are discussed. Particular calcuhtions are made for the caze Nz-C02(v3) vibrational energy exchange.
Molecular isotope effects in the thermal-energy charge exchange between He+ and N2
β Scribed by T.R. Govers; F.C. Fehsenfeld; D.L. Albritton; P.G. Fournier; J. Fournier
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 376 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The N+ and N; products of the thermal-energy reaction of He+ with I4 N2 and lsN2 have been examined by mass spectrometry and the emission from the product C'ZG state of r4N; and rsN; has been investigated by optical spectiometry.
A strong isotope effect is observed in both the N+/Nf ratio and the optical emission. Lower limits are placed on the production of excited N; states other than the C*Zc state.
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