Molecular interpretation of the behaviour of polyisobutylene in different solvents
β Scribed by T. Moussa; K. C. Tam; C. Tiu
- Publisher
- Springer-Verlag
- Year
- 1990
- Tongue
- English
- Weight
- 831 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0035-4511
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π SIMILAR VOLUMES
Scaled particle theory was used for calculating the enthalpy of cavity formation in the solvation process of hydroxyl cyclohexane derivatives in water and in organic solvents. From the values calculated for the enthalpy of formation of the cavity and from those quoted for the enthalpy of solvation,
vibration spectra arc used to asws solvent perturbation of DCI rotation in six hcxadecanc isomers of different molecular structure: R-CI~, 2-, 4-and S-methyipentadecane, C-pcntylundecane and 2,2,4,4,6,8,8-~~e~t~mctfiyino~ane. The rotation is sensitive to smalf. regions of the alkane surface whose di