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Vibration—Rotation spectra of DCl in hexadecane solvents of different molecular shapes

✍ Scribed by Dominique Richon; Donald Patterson

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
282 KB
Volume
46
Category
Article
ISSN
0009-2614

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✦ Synopsis

vibration spectra arc used to asws solvent perturbation of DCI rotation in six hcxadecanc isomers of different molecular structure: R-CI~, 2-, 4-and S-methyipentadecane, C-pcntylundecane and 2,2,4,4,6,8,8-~~e~t~mctfiyino~ane. The rotation is sensitive to smalf. regions of the alkane surface whose dimensions are comparable to those of DC& whereas properties such ins the molcculrtr opticat anisotropy and cotre$ation of mokcular orientation reelect rhc whole molecular envelope. P~ious work El-3 ] has shown that the vibrationrotation spectrum of DCI in alkanc sofvents depends

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