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Effect of solvent molecular structure on vibration—rotation spectra of DCl and CO solutes in cycloalkanes

✍ Scribed by Dominique Richon; Donald Patterson

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
673 KB
Volume
24
Category
Article
ISSN
0301-0104

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Vibration—Rotation spectra of DCl in hex
Vibration—Rotation spectra of DCl in hexadecane solvents of different molecular shapes
✍ Dominique Richon; Donald Patterson 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 282 KB

vibration spectra arc used to asws solvent perturbation of DCI rotation in six hcxadecanc isomers of different molecular structure: R-CI~, 2-, 4-and S-methyipentadecane, C-pcntylundecane and 2,2,4,4,6,8,8-~~e~t~mctfiyino~ane. The rotation is sensitive to smalf. regions of the alkane surface whose di