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Molecular constants of SiH3C ≡ CH and SiD3C ≡ CH

✍ Scribed by M. G. Krishna Pillai; K. Ramaswamy; S. G. Gnanadesikan


Book ID
112591742
Publisher
Springer
Year
1966
Tongue
English
Weight
335 KB
Volume
16
Category
Article
ISSN
0011-4626

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✍ Hui Zhang; Gui-Ling Zhang; Jing-Yao Liu; Miao Sun; Bo Liu; Ze-Sheng Li 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 211 KB 👁 2 views

## Abstract The multiple‐channel reactions SiH~3~ + SiH~3~CH~3~ → products and SiH~3~ + SiH~2~(CH~3~)~2~ → products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6‐31+G(d,p) level, and energetic information is further refined by the MC‐QCISD meth

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The methylfluoroacetylenes CH 3 -(CBC) 2 -F and CH 3 -(CBC) 3 -F have been generated for the first time in a pulseddischarge nozzle and characterized by molecular beam Fourier transform microwave spectroscopy in the 5-26 GHz frequency range. The spectroscopic constants B ¼ 1086:44824ð13Þ MHz, D J ¼