𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Molecular beam pulsed-discharge Fourier transform microwave spectra of CH3–CC–F, CH3–(CC)2–F, and CH3–(CC)3–F

✍ Scribed by Susana Blanco; M.Eugenia Sanz; Santiago Mata; Alberto Lesarri; Juan C. López; Helmut Dreizler; José L. Alonso

Book ID
104108182
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
236 KB
Volume
375
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The methylfluoroacetylenes CH 3 -(CBC) 2 -F and CH 3 -(CBC) 3 -F have been generated for the first time in a pulseddischarge nozzle and characterized by molecular beam Fourier transform microwave spectroscopy in the 5-26 GHz frequency range. The spectroscopic constants B ¼ 1086:44824ð13Þ MHz, D J ¼ 0:02044ð70Þ kHz, and D JK ¼ 7:083ð91Þ kHz of CH 3 -(CBC) 2 -F and B ¼ 478:908444ð34Þ MHz, D J ¼ 0:003060ð98Þ kHz, and D JK ¼ 1:899ð22Þ kHz of CH 3 -(CBC) 3 -F have been determined. In addition, the 13 C isotopic species of CH 3 -CBC-F in their natural abundances have been measured, and a partial substitution structure of CH 3 -CBC-F has been derived and compared with those of related fluorine derivatives.

📜 SIMILAR VOLUMES

Microwave Spectra of the Methylpolyynes
Microwave Spectra of the Methylpolyynes CH3(C≡C)4H and CH3(C≡C)5H
✍ M.J. Travers; W. Chen; J.-U. Grabow; M.C. McCarthy; P. Thaddeus 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 122 KB

Following the laboratory detection by Fourier transform microwave spectroscopy of the four new methylcyanopolyynes described in the accompanying paper by W. Chen et al. (J. Mol. Spectrosc. 1998), we detected two new methylpolyynes, CH3(C identical withC)4H and CH3(C identical withC)5H. The strongest

Microwave Spectra of the Methylpolyynes
Microwave Spectra of the Methylpolyynes CH3(CC)6H and CH3(CC)7H
✍ Wei Chen; M.C. McCarthy; Stewart E. Novick; P. Thaddeus 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 60 KB

Two new methylpolyynes, CH 3 (C'C) 6 H (tridecahexayne) and CH 3 (C'C) 7 H (pentadecaheptayne), have been detected in a supersonic molecular beam by Fourier transform microwave spectroscopy. A total of 20 transitions of CH 3 (C'C) 6 H in the K ϭ 0 and 1 rotational ladders and 8 transitions of CH 3 (