A systematic investigation on the structure and stability of the lowest singlet and triplet states of Si2H4 and SiH3SiH and the carbon analogous compounds SiH2CH2, SiH3CH, CH3SiH, C2H4, and CH3CH
β Scribed by Koehler, Hans Joachim; Lischka, Hans
- Book ID
- 127085337
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 676 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The multipleβchannel reactions SiH~3~ + SiH~3~CH~3~ β products and SiH~3~ + SiH~2~(CH~3~)~2~ β products are investigated by direct dynamics method. The minimum energy path (MEP) is calculated at the MP2/6β31+G(d,p) level, and energetic information is further refined by the MCβQCISD meth
Reaction rate constartls of SiHI(%'At) have been directly measured for the first time using the laser photolysis-laser-induced fluorescence method. The preparation of SiH: radical in the laser photolysis (193 m-n) or phenylsilane and the concentration of the radiczd is demonstrated by a dye laser at