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Molecular and Crystal Structure of Rubidium(dibenzo-18-crown-6)pentaiodide [Rb(C20H24O6)]I5.

✍ Scribed by Ingo Pantenburg; Karl-Friedrich Tebbe


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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The bonding in the As 6 4Γ€ ion is studied in the unusually low-coordination environment provided by the compound {Rb[18]crown-6)} 2 Rb 2 As 6 β€’6 NH 3 . Theoretical analysis of the related P 6 4Γ€ ion indicates an unusual PΒΌP bond which contains major contributions from the lone pairs. Outside a highl