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Modular Phosphite–Oxazoline/Oxazine Ligand Library for Asymmetric Pd-Catalyzed Allylic Substitution Reactions: Scope and Limitations—Origin of Enantioselectivity

✍ Scribed by Montserrat Diéguez; Oscar Pàmies


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
570 KB
Volume
14
Category
Article
ISSN
0947-6539

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Modular Furanoside Phosphite-Phosphoroam
✍ Eva Raluy; Oscar Pàmies; Montserrat Diéguez 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 2 views

## Abstract A library of furanoside phosphite‐phosphoroamidite ligands has been synthesized and screened in the palladium‐catalyzed allylic substitution reactions of several substrate types. These series of ligands can be prepared efficiently from easily accessible D‐xylose and D‐glucose. Their mod