Modified heterojunction based on zinc oxide thin film for hydrogen gas-sensor application
โ Scribed by S. Basu; A. Dutta
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 473 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0925-4005
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โฆ Synopsis
Device-quahty ZnO thm film IS deposlted by usmg an mdlgenously developed moddied CVD method and a Pd/ZnO/p-B heteropmctlon IS fabricated A study of the current-voltage characterlstlcs of the heterolunctlon m pure air and m air with different concentrations (2000-20 000 ppm) of hydrogen reveals that the device can be used as a room-temperature hydrogen sensor down to a level of hydrogen below Its explosron mucture mth an The saturatwn sensltlvlty and time response of the device wth respect to the dtierent hydrogen concentrattons m air has been studled The device operatmg at 1 V forward bias shows a maxLmum saturation sensltlvlty m different hydrogen concentrations At 20 000 ppm Hz m air, the sensltlvlty 1s found to be 5 x 102, while the time response IS 162 s The mcrease of surface ConductMly of ZnO at the Pd/ZnO Interface due to the adsorption and chemical mteractlon of hydrogen 1s found to play a key role m sensmg This mechamsm of hydrogen sensing 1s verdied by a double-metal-gate heterolunctlon
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Polycrystalline zinc oxide thin films with thicknesses in the range 0.3 ~m-1 #m were deposited on silicon and alumina substrates by a spray chemical vapour deposition method. The film was characterized for crystallinity, resistivity and carrier concentration. A modified heterostructure Pd/ZnO(0.38 ~
Nanostructured ZnO thin film was prepared by DC reactive magnetron sputtering and characterized by X-ray diffraction, SEM, AFM, FT-IR spectroscopy, UV-vis spectroscopy and photoluminescence measurements. Under the conditions employed, the sputtered ZnO film was found to be polycrystalline with grain