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Modified BINOL Ligands in Asymmetric Catalysis

✍ Scribed by Yu Chen; Shahla Yekta; Andrei K. Yudin

Publisher
John Wiley and Sons
Year
2003
Weight
50 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract Several N,P bidentate phosphite‐type ligands derived from readily available ferrocene‐based iminoalcohols were successfully used in Rh‐catalysed hydrogenations and Pd‐catalysed allylic substitutions of a variety of substrates. Moderate‐to‐high catalytic activities under standard conditi

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The development and application of a novel linked-1,1'-binaphthol (linked-BINOL) as an approach towards practical asymmetric multifunctional catalysis is described. Linked-BINOL was first designed to increase the stability of a Ga-Li-BINOL complex against ligand exchange with 4-methoxyphenol. An oxy