BINOL-Derived N-Phosphino Sulfoximines as Ligands for Asymmetric Catalysis.
โ Scribed by Manfred Reetz; Oleg G. Bondarev; Hans-Joachim Gais; Carsten Bolm
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 25 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
## Abstract Several N,P bidentate phosphiteโtype ligands derived from readily available ferroceneโbased iminoalcohols were successfully used in Rhโcatalysed hydrogenations and Pdโcatalysed allylic substitutions of a variety of substrates. Moderateโtoโhigh catalytic activities under standard conditi
## Abstract The intermolecular phosphaโMichael reaction of cyclic and acyclic alkenyl sulfoximines proceeds readily and yields the corresponding phosphanyl sulfoximines in good yield. The asymmetric induction provided by sulfoximine group in CโP bond formation is apparently only low. The configurat