Possible breakdown of the reaction coord
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S.-B. Zhu; G.W. Robinson
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Article
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1988
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Elsevier Science
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English
β 587 KB
In liquid-phase isomerization reactions, local departures from Maxwellian distributions appear to occur in different zones of the reaction coordinate chosen as dihedral angle connecting cis and trans forms. These deviations becomeappreciable for light masses and high barriers. The results partially