๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Possible breakdown of the reaction coordinate concept in condensed-phase chemistry

โœ Scribed by S.-B. Zhu; G.W. Robinson

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
587 KB
Volume
153
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

In liquid-phase isomerization reactions, local departures from Maxwellian distributions appear to occur in different zones of the reaction coordinate chosen as dihedral angle connecting cis and trans forms. These deviations becomeappreciable for light masses and high barriers. The results partially reflect the fact that the reaction coordinate derived from isolated-molecule considerations is a poor representation of the solution-phase dynamics.

๐Ÿ“œ SIMILAR VOLUMES

An approach to the understanding of radi
An approach to the understanding of radiation chemistry in the condensed phase
โœ Jacqueline O. Berg; G. Wilse Robinson ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 542 KB

This paper describes a purely electronic mechanism by which = 20 eV excitations in condensed phases relax to lower energy states. l-he mechanism utilizes an "energy fission" process whereby an ionic or excitonic state splits into two lower energy states, at least one being localized. The mechanism e

Modeling the Reactions of Energetic Mate
Modeling the Reactions of Energetic Materials in the Condensed Phase
โœ Laurence E. Fried; M. Riad Manaa; James P. Lewis ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons โš– 8 KB ๐Ÿ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.