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An approach to the understanding of radiation chemistry in the condensed phase

✍ Scribed by Jacqueline O. Berg; G. Wilse Robinson

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 542 KB
Volume: 34
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85257-2

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✦ Synopsis

This paper describes a purely electronic mechanism by which = 20 eV excitations in condensed phases relax to lower energy states. l-he mechanism utilizes an "energy fission" process whereby an ionic or excitonic state splits into two lower energy states, at least one being localized. The mechanism explains not only the known rapidity of such processes but also sup gests an explanation for the proportionation of the chemistry between ionic and electronically excited states.

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