Modelling of the inactivation kinetics of the trypsin inhibitors in soy flour
β Scribed by van den Hout, Rob; Meerdink, Gerrit; van 't Riet, Klaas
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 168 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0022-5142
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β¦ Synopsis
The inactivation kinetics of trypsin inhibitors (TIs) in soy Γ½our was measured over a large range of temperatures (80-134ΓC) and moisture contents (0.08-0.52 g (g ds)-1). The inactivation of TIs showed a two-phase inactivation behaviour. The inΓ½uence of moisture content on the inactivation rate of TIs was large at moisture contents AE 0.30 g (g ds)-1. Six diΓΎ erent inactivation kinetics models were used to describe the decrease of the trypsin inhibitor activity at constant moisture content. The models were compared statistically using a corrected Akaike information criterion. The most parsimonious models at moisture contents Γ0.30 g (g ds)-1 were the model with two ΓΌrst-order reactions each for a diΓΎ erent TI group, and the model with an irreversible inactivation of a native TI to a partially active intermediate TI, followed by a denaturation step. The nth order reaction model was favoured at moisture contents Γ0.40 g (g ds)-1. The kinetics parameters of the model with two ΓΌrstorder reactions were modelled as a function of moisture content. The overall inactivation model described well the experimental inactivation data of TIs.
π SIMILAR VOLUMES
A reaction mechanism for the photooxidation of dimethyldisulfide (DMDS) in aqueous acetonitrile has been established by kinetic modeling the UV absorbance vs. time curves under continuous irradiation. The model, built according to the known solution reactivity of oxysulfur radicals [1], consists of