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Role of water in the kinetic modeling of catalyst deactivation in the MTG process

✍ Scribed by Ana G. Gayubo; Andrés T. Aguayo; Angel L. Morán; Martín Olazar; Javier Bilbao


Publisher
American Institute of Chemical Engineers
Year
2002
Tongue
English
Weight
285 KB
Volume
48
Category
Article
ISSN
0001-1541

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A reaction mechanism for the photooxidation of dimethyldisulfide (DMDS) in aqueous acetonitrile has been established by kinetic modeling the UV absorbance vs. time curves under continuous irradiation. The model, built according to the known solution reactivity of oxysulfur radicals [1], consists of