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Modeling NMR chemical shifts: a comparison of charge models for solid state effects on 15N chemical shift tensors

✍ Scribed by Marta B Ferraro; Viviana Repetto; Julio C Facelli

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
62 KB
Volume
10
Category
Article
ISSN
0926-2040

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✦ Synopsis

This paper presents results from applying different point charge models to take into account intermolecular interactions to model the solid state effects on the 15N NMR chemical shifts tensors. The DFT approach with the BLYP gradient corrected exchange correlation functional has been used because it can include electron correlation effects at a reasonable cost and is able to reproduce 15N NMR chemical shifts with reasonable accuracy. The results obtained with the point charge models are compared with the experimental data and with results obtained using the cluster model, which includes explicitly neighboring molecular fragments. The results show that the point charge models can take into account solid state effects at a cost much lower than the cluster methods.

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