## Abstract The proton transfer equilibrium in a series of double Schiff base derivatives of __trans__‐1,2‐diaminocyclohexane in solution and the solid state was studied by means of ^15^N NMR spectroscopy and analysis of the deuterium isotope effect on the chemical shifts Δ^15^N(D). The presence of
Solid-state NMR study of Schiff base derivatives of 2-hydroxynaphthaldehyde. Deuterium isotope effects on 15N chemical shifts in the solid state
✍ Scribed by Z. Rozwadowski; W. Schilf; B. Kamieński
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 111 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.1594
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✦ Synopsis
Abstract
Schiff base derivatives of 2‐hydroxynaphthylaldehyde were studied by means of ^13^C and ^15^N cross‐polarization magic angle spinning NMR spectroscopy and deuterium isotope effects on ^15^N chemical shifts, ΔN(D), in the solid state. ΔN(D) in the solid state provided evidenced for the presence of a dynamic proton transfer equilibrium in the solid state at the room temperature. Copyright © 2005 John Wiley & Sons, Ltd.
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