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Mixtures of Chiral and Achiral Monodentate Ligands in Asymmetric Rh-Catalyzed Olefin Hydrogenation: Reversal of Enantioselectivity.

โœ Scribed by Manfred T. Reetz; Gerlinde Mehler

Publisher
John Wiley and Sons
Year
2003
Weight
122 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

๐Ÿ“œ SIMILAR VOLUMES

Mixtures of Configurationally Stable and
Mixtures of Configurationally Stable and Fluxional Atropisomeric Monodentate P Ligands in Asymmetric Rh-Catalyzed Olefin Hydrogenation
โœ Manfred T. Reetz; Xiaoguang Li ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 268 KB

Several years ago it was reported that monodentate phosphites, [1] phosphonites, [2] and phosphoramidites [3] derived from 2,2'-dihydroxy-1,1'-binaphthyl (BINOL) are efficient ligands in various Rh-catalyzed asymmetric olefin-hydrogenation reactions (90-99 % ee). These observations were surprising,