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Nonlinear Effects in Rh-Catalyzed Asymmetric Olefin Hydrogenation Using Mixtures of Chiral Monodentate P Ligands

✍ Scribed by Manfred T. Reetz; Yu Fu; Andreas Meiswinkel

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 254 KB
Volume: 45
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200503604

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## Abstract Six chiral monodentate ligands combining a 1,3‐dioxa‐2‐phosphacycloheptadinaphthyl moiety [(__R__)‐ or (__S__)‐binoP] either with a phenylalanine‐ or with an alanine‐derived fragment were synthesised. The new phosphoramidites are all relatively air stable. Related compounds in which the