Mixed Four-Coordinate Gold(I) Complexes with Diphosphines or Diphosphine Disulfides as Ligands. Crystal Structure of [Au{(PPh2)2C2B10H10}{(SPPh2)2CH2}]ClO4.cntdot.CH2Cl2

Synthesis of Silver(I) Complexes with th

Synthesis of Silver(I) Complexes with the Bis(diphenylphosphanyl)-o-carborane Ligand. Crystal Structure of [Ag(phen){(PPh2)2C2B10H10}]ClO4 and [Ag{(SPPh2)2CH2}{(PPh2)2C2B10H10}]ClO4 · CH2Cl2

✍ Bembenek, Eberhard ;Crespo, Olga ;Concepción Gimeno, M. ;Jones, Peter G. ;Laguna 📂 Article 📅 1994 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 549 KB

Silver(1) complexes I Bis(diphenylphosphany1)-o-carborane I o-Carborane Silver(1) perchlorate or nitrate react readily with bis(di-phenylphosphany1)-o-carborane to give the complexes [AgX((PPh2)2C2BloHlo)1 [X = C104 (l), NO3 (2)]. The perchlorate ligand is weakly bound to the silver atom and thus ca

Synthesis and Structure of[Au4(C6F5)2{(P

Synthesis and Structure of[Au4(C6F5)2{(PPh2)2CH}2(PPh3)2](ClO4)2.cntdot.4CH2Cl2, a Complex with Two Direct Gold-Gold Bonds

✍ Gimeno, M. Concepcion; Jimenez, Josefina; Jones, Peter G.; Laguna, Antonio; Lagu 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 431 KB

Gold(I) Complexes with the nido -Diphosp

Gold(I) Complexes with the nido -Diphosphino Ligand [7,8-(Ph 2 P) 2 -7,8-C 2 B 9 H 10 ] - . Preparation of the First Metallocarborane Complex of this Ligand. Crystal Structures of [Au{(PPh 2 ) 2 C 2 B 9 H 10 }(PPh 3 )]·CH 2 Cl 2 and [Au 2 {(PPh 2 ) 2 C 2 B 9 H 10 } 2 {(PPh 2 ) 2 (CH 2 ) 3 }]·3Me 2 CO

✍ Crespo, Olga; Gimeno, M. Concepción; Jones, Peter G.; Laguna, Antonio 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 175 KB

Reactions of [Au(acac)PPh3] with diphosp

Reactions of [Au(acac)PPh3] with diphosphine derivatives: different coordination modes of gold to the ligand systems. X-ray structure of [SPPh2C(AuPPh3)2PPh2CH(AuPPh3)COOMe]ClO4 and [Au5(C6F5){(SPPh2)2C}2(PPh3)]

✍ Gimeno, M. Concepcion; Laguna, Antonio; Laguna, Mariano; Sanmartin, Federico; Jo 📂 Article 📅 1993 🏛 American Chemical Society 🌐 English ⚖ 914 KB

Synthesis and Characterization of Gold(I

Synthesis and Characterization of Gold(I) Complexes with the Ligand 1,2-Dithiolate- o -carborane. Crystal Structures of [Au 2 (μ-S 2 C 2 B 10 H 10 )(PPh 3 ) 2 ], [Au 2 (μ-S 2 C 2 B 10 H 10 )(μ-{(PPh 2 ) 2 (CHCH)}], and [Au 2 (μ-S 2 C 2 B 10 H 10 )(μ-{(PPh 2 ) 2 (C 6 H 4 )}]

✍ Crespo, Olga; Gimeno, M. Concepción; Jones, Peter G.; Ahrens, Birte; Laguna, Ant 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 215 KB

Reactions of [Au(acac)PPh3] with diphosp

Reactions of [Au(acac)PPh3] with diphosphine derivatives: different coordination modes of gold to the ligand systems. X-ray structure of [SPPh2C(AuPPh3)2PPh2CH(AuPPh3)COOMe]ClO4 and [Au5(C6F5)((SPPh2)2C)2(PPh3)]. [Erratum to document cited in CA119(19):203522v]

✍ Gimeno, M. Concepcion; Laguna, Antonio; Laguna, Mariano; Sanmartin, Federico; Jo 📂 Article 📅 1994 🏛 American Chemical Society 🌐 English ⚖ 46 KB