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Millimeter-Wave Spectrum of Fluorodiacetylene (HCCCCF)

✍ Scribed by Toshiaki Okabayashi; Noriko Yamashita; Yoshiko Sakai; Mitsutoshi Tanimoto

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
125 KB
Volume
193
Category
Article
ISSN
0022-2852

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✦ Synopsis

The millimeter-wave spectrum of HCCCCF was observed in the ground state as well as in the low-lying vibrationally excited states nu7, nu8, nu9 and also associated nu8 + nu9, 2nu9, and 3nu9 states. The HCCCCF molecule was produced by a dc glow discharge in a flowing vapor of 2,3,4,5,6-pentafluorostyrene. The l-type doubling constants determined are in good agreement with the values predicted from the harmonic force field calculation. Copyright 1999 Academic Press.

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