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Millimeter-wave spectrum and internal rotation of 1-silylpropyne, CH3CCSiH3

✍ Scribed by Jun Nakagawa; Koichi Yamada; Manfred Bester; Gisbert Winnewisser


Book ID
107802311
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
636 KB
Volume
110
Category
Article
ISSN
0022-2852

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The Millimeter- and Submillimeter-Wave R
✍ R. Bocquet; J. Burie; W.D. Chen; G. Wlodarczak; J. Demaison 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 309 KB

The ground state rotational spectrum of \(\mathrm{CH}_{3} \mathrm{CF}_{3}\) was measured from \(190 \mathrm{GHz}, J=18\), up to \(910 \mathrm{GHz}, J=87\) and \(K=63\). These measurements allow us to determine accurate molecular constants, including the three sextic centrifugal distortion constants: