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ChemInform Abstract: The Millimeter- and Submillimeter-Wave Rotational Spectrum of CH3CF3: Observation of the K = 3 Splitting.

โœ Scribed by R. BOCQUET; J. BURIE; W. D. CHEN; G. WLODARCZAK; J. DEMAISON

Book ID
112021066
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
26
Category
Article
ISSN
0931-7597

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The Millimeter- and Submillimeter-Wave R
The Millimeter- and Submillimeter-Wave Rotational Spectrum of CH3CF3: Observation of the K = 3 Splitting
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The ground state rotational spectrum of \(\mathrm{CH}_{3} \mathrm{CF}_{3}\) was measured from \(190 \mathrm{GHz}, J=18\), up to \(910 \mathrm{GHz}, J=87\) and \(K=63\). These measurements allow us to determine accurate molecular constants, including the three sextic centrifugal distortion constants:

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The millimeter- and submillimeter-wave spectrum of the ground and \(v_{2}=1\) vibrational excited state of \(\mathrm{PF}_{3}\) has been observed and analyzed. A centrifugal distortion analysis of the spectra extended up to the octic terms allowed an accurate determination of the spectroscopic consta

The Rotational Spectrum of CHF3 in the S
The Rotational Spectrum of CHF3 in the Submillimeter-Wave and Far-Infrared Region: Observation of the K = 3 Line Splitting
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The milimeter-wave, submillimeter-wave, and FIR spectra of the ground state of \(\mathrm{CHF}_{3}\) have been observed and analyzed up to \(J=78\). The resulting spectroscopic constants are: \(B_{0} / \mathrm{MHz}=\) \(10348.8706(2), D_{j} / \mathrm{kHz}=11.34482(13), D_{J K} / \mathrm{kHz}=-18.1176

Millimeter and submillimeter-wave spectr
Millimeter and submillimeter-wave spectrum of CHCl3. Determination of the h3 splitting constant
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The millimeter and submillimeter-wave spectrum of the ground state of CHJSCl, has been observed and analyzed up to J= 106. Theresultingspectroscopicconstantsare(inMHz):~=3302.07587(12),0,=1.511716( 66)~10~~,D,,=-2.51757(20)~10-~, H~~~=O.l268(12)~10-\*, HJJK= -0.5000(30)~10-', H~=O.652(11)~10-\*, L,=