Mid- to High-Valent Imido and Nitrido Complexes of Iron
✍ Scribed by Mark P. Mehn; Jonas C. Peters
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Orgunometalks 4 (1985) 2 102, and references cited therein. [lo] 3 is triclinic, space group Pi, u=6.848(1), b=8.412(1), c = 13.353(2) A, a=9?.74(1), /i= 100.14(1), y = lll.21(l)o, Y=700.7 A', p r , l , c ~= 1.489 g cm ' for 2 = 2 at -4O"C, F(000)=324,~~(Mo,,)=S.I cm-'. 2468 independent reflections
## Abstract An unprecedented alkyne–nitrile metathesis takes place when the high‐valent iron‐nitrido dication [Fe(L)N]^2+^, with L=2,6‐bis(2‐methyl‐1,3‐diaminopropan‐2‐yl)pyridine, is reacted with alkynes in the gas phase under thermal conditions. While the detailed role of the alkyne substrate wit