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High-Valent Iron and Manganese Complexes of Porphyrins and Related Macrocycles

✍ Scribed by Raymond Weiss; Avram Gold; Alfred X. Trautwein; James Terner


Publisher
John Wiley and Sons
Year
2003
Weight
51 KB
Volume
34
Category
Article
ISSN
0931-7597

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The term β€˜high-valent’ refers to iron complexes of porphyrins and related macrocycles in which the oxidation state of the iron center exceeds III. High-valent iron porphyrins and chlorins are important biological transients whose intermediacy has been demonstrated in numerous peroxidase and catalase

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