Reductive Carbonylation of High-Valent Oxorhenium Complexes—a New Route to Low-Valent Carbonylrhenium Compounds

✍ Scribed by Prof. Dr. Wolfgang A. Herrmann; Ulrich Küsthardt; Adolf Schäfer; Dr. Eberhardt Herdtweck

• Publisher: John Wiley and Sons
• Year: 1986
• Tongue: English
• Weight: 238 KB
• Volume: 25
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.198608171

✦ Synopsis

Orgunometalks 4 (1985) 2 102, and references cited therein.

[lo] 3 is triclinic, space group Pi, u=6.848(1), b=8.412(1), c = 13.353(2) A, a=9?.74(1), /i= 100.14(1), y = lll.21(l)o, Y=700.7 A', p r , l , c ~= 1.489 g cm ' for 2 = 2 at -4O"C, F(000)=324,~~(Mo,,)=S.I cm-'. 2468 independent reflections, 2232 "observed" with 12 2.00(1), Lorentz and empirical absorption correction (0 scan, Am= 1.4'. +h, +k, i l , (sin,9/ ,i),,,,,,=0.595, Mo,,,, A=0.71069 A). Patterson methods, Rz0.042, R , =0.056, w=[u'(F,,)+0.00013F2]-' for 181 refined parameters (anisotropic. H constant, A&,.= +0.99/-0.28 e/A', SHELX 76). Further details of the crystal structure investigation may be obtained from the Fachinforrnationszentrum Energie, Physik, Mathematik GmbH, D-7514 Eggenstein-Leopoldshafen 2 (FRG), on quoting the depository number CSD 51 952, the names of the authors, and the journal citation.

[ I I] Cf. Cr-C 2.168(8) and 2.185(6) A in (q'maleic acid)(q"-mesitylene).