✦ LIBER ✦

Microwave structure determination and quadrupole coupling measurements on acetylene-HCN and ethylene-HCN complexes

✍ Scribed by S.G. Kukolich; P.D. Aldrich; W.G. Read; E.J. Cambell

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 290 KB
Volume: 90
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83062-5

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✦ Synopsis

h!~aowaw rotational spectra for the compJe\es HCCH-HCN, HCCH-DCN, DCCD-HCN. HzCCHz -HCN and H2CCH2-DCN wcrc observed usmg a pulsed nozzle Fourier transform spcctromctcr. The dlstancc from the HCN carbon atom to the ccntcr of mass IS 3.655(10) A for sce~ylcnc-HCN and 3.709(10) A for ethylen+HCN Borh complc\ are Tskpcd wirh the HCN hydrogen atom closest to the C-C bond. The HCN aus 1s pcrpendxulx lo the pJanc of cthylcnc for ethylcnc-HCN Nltrogcn and dcuteaum quadrupok couphng aas mcasurcd.

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