✦ LIBER ✦

Dipole moment enhancement on formation of a hydrogen-bonded complex. Demonstration and measurement of the effect for HCN…HF by microwave spectroscopy

✍ Scribed by A.C. Legon; D.J. Millen; S.C. Rogers

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 241 KB
Volume: 41
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85265-7

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✦ Synopsis

The microwave spectrum of the heterodimer EKYbMF is reported, the collinearity of the nuclei establislIed, and ro(N--F) = 2.796 A obtained. From the Stark effect, ~10 (tiCN4iF) = 5.59 r 0.02 D which indicates an enhancement of 0.78 D over the vector sum of the monomer values.