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Microwave spectroscopic study of the SiF radical

✍ Scribed by Mitsutoshi Tanimoto; Shuji Saito; Yasuki Endo; Eizi Hirota

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 500 KB
Volume: 100
Category: Article
ISSN: 0022-2852
DOI: 10.1016/0022-2852(83)90037-1

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## Abstract Raman spectra of oriented single crystals of (NH~4~)~2~SiF~6~ are reported for the temperature range 440–20 K. The trigonal phase stable below 278 K undergoes a transition at 38.6 K. The changes in the spectra show that the symmetry does not remain trigonal, but give evidence for a lowe