Dispersed fluorescence studies on the 6 -X 6 and 6 -X 6 systems of the FeF radical have resulted in the observation of vibrational progressions for transitions to the X 6 state as well as at least two previously unobserved electronic states about 5000 cm -1 above the ground state. The states are ass
Low-lying electronic states of the SiF3 radical
โ Scribed by S.P. So
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 373 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The spectroscopic constants for the triplet and singlet states of LiB below about 30000 cm-~ are determined using an intemally contracted multireference configuration-interaction approach. The ground state is 311 as found in previous work. Transitions between the 311 state and the (1)3E-, (2)3II, an
The equilibrium geometries, excitation energies, force constants, and vibrational frequencies of the low-lying electronic states X2B1, 2A1, 2B2, and 2A2 of the PF2 radical have been calculated at the MRSDCI level with a double zeta plus polarization basis set. Our calculated geometry, force constant
## Relativistic CI calculations on the low-lying states of BiF(O+, 1, 2, O+ (II)) arising from the Q\*P\* configuration are carried out. Comparison calculations of the X-s states without spin-orbit interaction (3Z-, IX+ and 'A) are also presented. These calculations enable the assignment of three