Microbial cooxidation of naphthalene for the production of 1,2-dihydroxy-1,2-dihydronaphthalene
✍ Scribed by J.H. Hsieh; S.S. Wang
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 545 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0141-0229
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Photooxygenation of 1,2-dihydronaphthalenes resulted in diendoperoxides and hydroperoxides via [ 4 + 2 ] cycloaddition and ene reactions, respectively. The relative conÐguration and stereochemistry of the products were elucidated by various 1H and 13C NMR methods.
Recently Cookson and Coworkers' reported their results from the photolysis of 1,2dihydronapthalene (I). They found that irradiation of a solution of I, with unfiltered light from a medium pressure mercury lamp, resulted in the formation of bicyclohexene (II) and they provided some very convincing ev
## Abstract The conformational equilibria of 1‐ and 2‐phenyl‐1,2‐dihydronaphthalene (**1** and **2**) have been studied using 500 MHz ^1^H NMR spectroscopy. The signals due to the protons at C(1) and C(2) of compound **2** and of a deuterated derivative of **1** (3,4‐d~2~‐1) were analysed as ABX p
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