The photochemistry of 1,2-dihydronaphthalene
β Scribed by K. Salisbury
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 107 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Recently Cookson and Coworkers' reported their results from the photolysis of 1,2dihydronapthalene (I). They found that irradiation of a solution of I, with unfiltered light from a medium pressure mercury lamp, resulted in the formation of bicyclohexene (II) and they provided some very convincing evidence for the mechanism involved.
π SIMILAR VOLUMES
On account of recent interest in the photochemical reactivity of l,Z-dihydronaphthalenes 1.2 we wish to report the results of our experiments. A.
In a previous paper, 2 we have described the first photochemical 1,2-silyl migration together with generation of a disilene intermediate from &.
## Abstract The synthetic usefulness of the deprotonation/protonation reaction of excited 1,2βdihydronaphthalenes into 1,4βdihydronaphthalenes induced by amines has been investigated using 13 different substituted 1,2βdihydronaphthalenes and related compounds. The yield of the rearrangement ranges