Recently Cookson and Coworkers' reported their results from the photolysis of 1,2dihydronapthalene (I). They found that irradiation of a solution of I, with unfiltered light from a medium pressure mercury lamp, resulted in the formation of bicyclohexene (II) and they provided some very convincing ev
Photochemistry of some 1,2-dihydronaphthalenes
β Scribed by H. Kleinhuis; R.L.C. Wijting; E. Havinga
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 161 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
β¦ Synopsis
On account of recent interest in the photochemical reactivity of l,Z-dihydronaphthalenes 1.2 we wish to report the results of our experiments.
A.
π SIMILAR VOLUMES
In a previous paper, 2 we have described the first photochemical 1,2-silyl migration together with generation of a disilene intermediate from &.
## Abstract The synthetic usefulness of the deprotonation/protonation reaction of excited 1,2βdihydronaphthalenes into 1,4βdihydronaphthalenes induced by amines has been investigated using 13 different substituted 1,2βdihydronaphthalenes and related compounds. The yield of the rearrangement ranges