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[(Methyldiphenylphosphonio)methanide]tris(pentafluorophenyl)gold(III) acetone solvate

✍ Scribed by Jones, P. G.


Book ID
114509116
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
332 KB
Volume
48
Category
Article
ISSN
0108-2701

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Tris­(penta­fluoro­phenyl)[2-(di­phenyl­
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Single-crystal X-ray study T = 143 K Mean '(C±C) = 0.008 A Ê Disorder in solvent or counterion R factor = 0.032 wR factor = 0.072 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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H atoms were included using a riding model with fixed C-H bond lengths of 0.95 (phenyl), 0.99 (methylene), 1.00 A ˚(CHCl 3 ); U iso (H) values were fixed at 1.2 times U eq of the parent atom. To improve refinement stability, a total of 562 restraints were applied to C atom displacement parameters (s

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The title compound, [Re(C 7 H 12 NO 2 S 3 )(C 18 H 15 P)]ÁC 3 H 6 O, crystallizes from a solution in chloroform-acetone-cyclohexane with enantiomers disordered equally over each molecular site. Hydrogen bonds between the carboxyl groups form dimers in the crystal structure.