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[2-Carb­oxy-2,2′,2′′-nitrilo­tris(ethanethiol­ato)-κ4N,S,S′,S′′](triphenyl­phosphine-κP)rhenium(III) acetone solvate

✍ Scribed by Schiller, Eik ;Kraus, Werner ;Reck, Günter ;Spies, Hartmut ;Pietzsch, Hans-Jürgen

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
205 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Re(C 7 H 12 NO 2 S 3 )(C 18 H 15 P)]ÁC 3 H 6 O, crystallizes from a solution in chloroform-acetone-cyclohexane with enantiomers disordered equally over each molecular site. Hydrogen bonds between the carboxyl groups form dimers in the crystal structure.

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A new polymorph of fac-tris(4,6-di­methy
A new polymorph of fac-tris(4,6-di­methyl­pyrimidine-2-thiol­ato-κ2N,S)­cobalt(III) monohydrate
✍ Burrow, Robert Alan ;Schulz Lang, Ernesto ;Fernandes Jr, Ramão Marceli ;Vázquez- 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 421 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.011 A Ê R factor = 0.061 wR factor = 0.139 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.