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Methylation of a nitrosylruthenium complex bearing a hydridotris(pyrazolyl)borate ligand

✍ Scribed by Arikawa, Yasuhiro; Yamaguchi, Soseki; Haige, Ryohei; Oshiro, Eriko; Umakoshi, Keisuke; Onishi, Masayoshi


Book ID
121510522
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
461 KB
Volume
755
Category
Article
ISSN
0022-328X

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The hydride complexes Tp\*RuH(H,), (1) and Tp\*RuH(COD) (2) (Tp\* = hydridotris(3,5dimethyl)pyrazolyl borate) show good catalytic activity for the reduction of unactivated ketones either by dihydrogen or by hydrogen transfer from alcohols in basic media.