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Cyclometalation of a Pyrazolyl Arm in Hydridotris(1-pyrazolyl)borate and Tris(1-pyrazolyl)methane Complexes of Iridium

✍ Scribed by Heinekey, D. M.; Oldham, Warren J.; Wiley, Jackson S.


Book ID
126121240
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
126 KB
Volume
118
Category
Article
ISSN
0002-7863

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## Abstract By treating tris(1‐pyrazolyl)methane (tpm) with suitably activated [Ru(cod)(cot)] and [Ru(cod)(nap)] (cod = η^4^‐cycloocta‐1,5‐diene, cot = η^6^‐cycloocta‐1,3,5‐triene, nap = η^6^‐naphthalene) the (hydrido)Ru^II^ species [Ru(__N^2^__,__N^2′^__,__C^5″^__‐tpm)(cod)H] with cyclometalated t