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Structural and Electronic Differences of Copper(I) Complexes with Tris(pyrazolyl)methane and Hydrotris(pyrazolyl)borate Ligands

โœ Scribed by Fujisawa, Kiyoshi; Ono, Tetsuya; Ishikawa, Yoko; Amir, Nagina; Miyashita, Yoshitaro; Okamoto, Ken-ichi; Lehnert, Nicolai


Book ID
121313182
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
353 KB
Volume
45
Category
Article
ISSN
0020-1669

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Tris(pyrazolyl)methane Ligands: Synthese
โœ Alberto Sรกnchez-Mรฉndez; Gustavoย F. Silvestri; Ernesto deย Jesรบs; F.ย Javier deย laย  ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 197 KB

## Abstract The substituted ligands Me~3~SiC(pz)~3~ (1) and Me~3~SiOCH~2~C(pz)~3~ (2) have been prepared starting from HC(pz)~3~ and HOCH~2~C(pz)~3~. The molecular structure of compound 1 has been determined by Xโ€ray diffraction studies, which show a propellerโ€like conformation of the pyrazolyl rin