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Methyl Substitutent Effects in Radical Cation Diels−Alder Reactions

✍ Scribed by Valley, Nicholas A.; Wiest, Olaf


Book ID
126126693
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
380 KB
Volume
72
Category
Article
ISSN
0022-3263

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✍ Bijan Harirchian; Nathan L Bauld 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 181 KB

The first examples of intramolecular cation radical Die&-Alder reactions have been established using trienes which cyclize to hydroindane systems. The extremely high endo stereoselectivity characteristic of the cation radical Diels-Alder reaction is effectively exploited to generate trans-hydroinda